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Strong and Dynamic CO2 Sorption in a Flexible Porous Framework Possessing Guest Chelating Claws

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WOS被引频次:175
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成果类型:
期刊论文
作者:
Liao, Pei-Qin;Zhou, Dong-Dong;Zhu, Ai-Xin;Jiang, Lu;Lin, Rui-Biao;Zhang, Jie-Peng;Chen, Xiao-Ming
通讯作者:
Zhang, JP
作者机构:
[Liao, Pei-Qin; Chen, Xiao-Ming; Lin, Rui-Biao; Jiang, Lu; Zhang, Jie-Peng; Zhou, Dong-Dong; Zhu, Ai-Xin] MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
[Zhu, Ai-Xin] Faculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650092, China
通讯机构:
[Zhang, JP] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China.
语种:
英文
关键词:
Adsorption enthalpies - Chelating sites - Functionalized - Porous coordination polymer - Single crystal x-ray diffraction
期刊:
Journal of the American Chemical Society
ISSN:
0002-7863
年:
2012
卷:
134
期:
42
页码:
17380-17383
文献类别:
WOS:Article;EI:Journal article (JA)
所属学科:
ESI学科类别:化学;WOS学科类别:Chemistry, Multidisciplinary
入藏号:
WOS:000310103800013;EI:20124415615810;PMID:23039713
基金类别:
973 Project [2012CB821706]; National Natural Science Foundation of China [21121061, 21001120]
机构署名:
本校为其他机构
院系归属:
化学化工学院
摘要:
Using a bis-triazolate ligand and tetrahedral Zn(II) ion, we synthesized a flexible porous coordination polymer functionalized with pairs of uncoordinated triazolate N-donors that can be used as guest chelating sites to give very high CO<inf>2</inf> adsorption enthalpy and CO<inf>2</inf>/N<inf>2</inf> selectivity. The dynamic CO<inf>2</inf> sorption behavior could be monitored well by single-crystal X-ray diffraction. &copy;2012 American Chemical Society.
参考文献:
An J., 2009, J AM CHEM SOC, V132, P38
An J, 2010, J AM CHEM SOC, V132, P5578, DOI 10.1021/ja1012992
Arstad B, 2008, ADSORPTION, V14, P755, DOI 10.1007/s10450-008-9137-6
Bae YS, 2008, CHEM COMMUN, P4135, DOI 10.1039/b805785k
BLOOR JE, 1968, J PHYS CHEM-US, V72, P716, DOI 10.1021/j100848a054

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